New oil absorbent uses nanotechnology

A next-generation material first initially developed for use in electronics has proven itself a capable oil absorbent for polluted waters. The new material Boron Nitride, or “white graphene”, is similar in structure to its namesake Graphene consisting of a Nano sheet of single bonded atoms laid out like a chain-link fence. A recent research report claims that when these sheets are combined it forms a coarse white powder that can soak up organic pollutants such as industrial chemicals and oil.

Boron Nitride itself is obviously not new to science but when arranged in porous Nano sheets, the white powder vastly outperformed commercially available chunks of boron nitride. In tests the powder soaked up as much as 33 times its own weight in the chemical ethylene glycol and 29 times its own weight of engine oil. Better still the saturated powder also floats on water.

According to the authors of the research these properties make these porous Boron Nitride Nano sheets suitable for a wide range of applications in spill control, water purification and effluent treatment.

The research is an extension of the groundbreaking discovery of Graphene, the most well-known two dimensional nano material consisting of a single layer of carbon atoms arranged in a honeycomb structure. It is the thinnest material known to man and yet is also one of the strongest. Apparently it would take an elephant standing on a pin to pierce the sheet – not something you can try at home!

As was the case with graphene the key question is whether the stuff can be manufactured commercially at an economic price to challenge existing product technology in this case the tried and tested specialist oil and chemical absorbents currently available. It’s a long and no doubt costly journey from the research lab to the market place but we wish the researchers luck.

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Marinas and leisure boat operators under scrutiny.

The Environment Agency and regional water companies have a statutory responsibility to enforce controls on any business activity that produces waste water generically called “trade effluent” and failure to comply with regulations may result in significant fines to your business. Added to which you have the European Water Framework Directive that was signed into law by all European Union countries in the year 2000. The Directive set an initial time frame for implementation of water improvement frameworks, which had to be operational by the end of 2012, with the detailed objectives being achieved by the end of 2015.

Marinas, commercial and leisure boat operators have a particularly hard time when it comes to compliance given the pollution potential they generate in the normal course of business. Potential sources of pollutants commonly found in many marinas include oil, fuel, boat sewage, toxic metals, solvents, antifreeze, and detergents. As figures show water pollution is on an upward curve the Environment Agency is stepping up its inspections to ensure all marina and boatyard businesses address this problem.

The best way to minimise accidental pollution is to put in place an Environmental Management Plan based on a thorough risk assessment of your business operations. Effective environmental protection is easier if you have a structured documented management plan that the workforce can refer to.

Achieving practical outcomes is based on four stages.
Identify the potential risks and environmental impact
Implement safeguards and controls including staff training and customer awareness.
Check and monitor safeguards regularly to ensure compliance with your management plan
Review your plan and adapt to changing working practices or new risks.

Ensuring environmental safety is often common sense. Siting oil and fuel tanks as far away from water courses as possible is an obvious example but you should also ensure tanks have bunds with sufficient capacity to contain any spillage. Choose spill control products appropriate to the risk and site them in close proximity to the risk. Oil only spill absorbents for example are not effective on water based effluents and no control measures will be effective if they are not readily accessible. Ensure customers, particularly boat owners on your moorings are aware of their responsibilities and know the type and location of spill control provisions available on site. You can also encourage customers to carry their own spill control kits which you can supply.

We all have a responsibility to protect the environment and after all the industry rely on having safe clean waterways to attract more boating enthusiasts.

 

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Choosing the right Absorbent solution.

A quick browse through our web site will show hundreds of solutions for tackling spills. The challenge is to ensure the spill control solutions you choose are suitable for the spill risks identified for your specific spill risks.

General purpose absorbent granules are a popular choice but you can further improve the protection by choosing granules designed for specific types of spills and applications. The New Safety Tread granules are highly effective on chemical spills whereas the XR99 Highway granules present a low skid risk when deployed on road surfaces and comply with European Road Safety Regulations. Similarly the Spill Fix loose granules are designed to combat all types of hydrocarbon spills and ounce for ounce have 50% more absorbent capability than standard clay granules.
The Oil and Chemical only absorbent ranges are not just different colour options of the General Purpose products although their distinctive colours do make them easier to identify in an emergency. For oil storage facilities, water pollution control, boatyards and transport depots Oil only absorbents not only attract and absorb oils (oleophilic) but unlike general purpose absorbents have the added advantage of being water repellent (hydrophobic) so they only absorb the oil making them more efficient and making disposal easier. Our specialised Chemical Absorbents for aggressive acids, alkalis and solvents employ chemically inert materials that won’t break down in use and, like the oil only products, are also hydrophobic.

It should be said that for small spill risks for example around industrial machinery, workshops and process areas, potentially involving a variety of hazardous substances the general purpose range will suffice as they will absorb water, lighter grade hydrocarbons and chemicals. It is when the potential risk to property and employees from spills or the potential for environmental damage escalates that you should seriously consider specialist absorbents in your spill management thinking.

Hopefully being aware of the options will help you determine the best choice for your application.

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Mineral Oil Spill blamed for bird contamination

Hundreds of seabirds washed up in an oil spill on the south coast from Sussex to Cornwall on Thursday 31st January were contaminated with a waxy substance that is now believed to be a mixture of refined mineral oils, most probably jettisoned from a ship passing through the Western approaches to the English Channel.
A major rescue operation has been launched by the RSPCA and other local charities to capture and clean the affected birds. Inevitably it is highly likely that many more birds have perished out to sea than have been rescued and even then it has proved such a major task to remove the contamination that not all the birds rescued will survive.

Preventing environmental pollution both on land and sea is now given top priority and the Maritime and Coastguard Agency have sent a counter pollution surveillance aircraft to investigate the sea areas between Dover and the Isles of Scilly looking for the source. Shipping schedules and cargo records are also being scoured to try and pinpoint the culprit.
The fact that the captain of the vessel did not report the spill suggests it was not accidental and more likely to do with saving money. Let’s hope the authorities can track the ship down and prosecute the offender at least as a deterrent to others. Sadly as far as the Guillemots are concerned the damage is already done and worse still right at the start of the breeding season.
The incident, and the expensive resources put behind locating the source should act as a reminder to all those involved in the transport, storage and use of oils, fuels and other hazardous materials. It is a legal obligation to ensure appropriate spill control and containment measures such as absorbent products, bunds and spill kits are in place should a spill occur.

The Environment Agency is ever more vigilant and can force the perpetrator to foot the bill for environmental pollution caused by careless or irresponsible actions.

Conducting a spill risk assessment to help formulate a coherent spill control management system is the only sensible approach and will protect the viability of the business as well as the environment.

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How to Remove Oil Spills and Stains.

With the first snows of winter forecast for this week I decided to stock up my log store. I had some large boughs on the drying rack ready for cutting. Trying to burn fresh cut “green” wood on an open fire is hopeless so I always have logs seasoning for at least 3 months prior to winters arrival.

The chain saw needed a quick sharpen and I topped up the saws chain oil container. Believe me the saw cuts far better and stays sharp longer if chain oil is used. I don’t quite know how but I clearly forgot to replace the oil cap. The first I knew of it was when my wife pointed out the sinuous trail of oil snaking across the paved drive between the garage and the wood store. It was probably less than 100ml in total but what an unsightly mess it looked.


Having written extensively on oil spills in the past I knew that the quicker the stain gets attention the better the outcome. There are loads of oil stain removal products on the market but I doubt anyone would be lucky enough to have a bottle on the shelf for such an event. I certainly did not.

So what to do. The first step is to remove as much of the fresh wet oil as possible. Use an absorbent wipe or absorbent pad preferably commercial grade. I have a roll of the Eez Off Heavy duty wipes that I find the best all-rounder for the workshop and garage. Lay it over the oil and dab rather than scrub as this just spreads the stain. The next step is to sprinkle over absorbent granules to draw out the oil. You will be surprised how many common household products can be applied.

Cat litter is often used (if you have a cat as we do) but I find it too coarse and suggest putting some in a plastic bag and crushing it with a rolling pin to a finer consistency before applying to maximise the surface contact area. You will need to leave it for a day or two and unfortunately if it rains the resultant slush makes an even bigger mess than the oil and on a windy day it will just blow away. I have also heard of people using dry cement, baking soda, talcum powder, oven cleaner and even salt but have never tried them myself.

Once the oil is dry you can also use a laundry powder detergent. Sprinkle the detergent onto the stain, add a small amount of water to make paste, scrub it into the stain using a stiff brush and leave it overnight. Wipe off the excess and hose down. I have also heard that pouring Cola on the stain is effective but it seems unlikely unless you know different.

Lastly check the type of oil being used. Increasingly modern oils including Chain oils are biodegradable so if you are still left will a faint stain over time the elements will work on the oil until it disappears naturally, although think months rather than days.

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